Quantum Mechanics - Axiomatic Formulation

Overview


State of a Quantum System


The state of a quantum system is a unit vector in a complex Hilbert space. Following Dirac, this is usually denoted as a Dirac ket.
{% | \psi > %}

Observable


Observable properties of the system are represented by operators on the Hilbert space. When the state of the system is one of the eigenvectors of the observable, then the system is guaranteed to be observed with the observable equal to the eigenvalue corresponding to the given eigenvector. The eigenvectors are assumed to form a complete orthogonal basis for the Hilbert space.

  • {% A |a {>} = a | a {>} %}
    - eigenvectors are states with a definite value for the observable {% A %} given by the eigenvalue {% a %}
  • {% {<} a | a' {>} = \delta(a- a') %}
    - eigenvectors are orthogonal
  • {% \int da |a {>} {<} a | = 1 %}
    - eigenvectors form a complete basis


When the system is not in an eigenvector of the observable operator, then it can be expressed as a linear combination of the eigenvectors.
{% | \psi {>} \; = \sum_i a_i | \phi_i > %}
When an observation corresponding the given observable is made, the system will collapse into one of the eigenvectors states and be observable will be seen to be the eigenvalue corresponding to that state. The probability that the state collapses to any given state {% | \phi > %} is given by the inner product associated with the Hilbert space squared.
{% | {<} \phi | \psi {>} | ^2 %}
The probability amplitude is defined to be
{% {<} \phi | \psi {>} %}
which is a complex number.

Commuting Observables


Position and Momentum


When a particle is observed at a particular point {% q %}, the state then collapses into a vector that represents the given point, using Diracs notation, {% | q {>} %} .

Likewise, if the point is measured to have a given momentum {% p %}, it will then be in the state {% | p {>} %}

Topics


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